This paper will focus on the development of a reactor model that describes the approach to. Advanced modelling and optimisation of natural gas. It was desired to construct a simulation of a methane autothermal reforming system to identify potential design issues and obtain a preliminary estimate of. Need to match the heat release rate with the steam hydrocarbon reforming rate. Kinetics, catalysis and mechanism of methane steam reforming. Tubular reforming and autothermal reforming of natural gas an. Cameron, in studies in surface science and catalysis, 2001. Chapter 1 introduction this thesis presents a master of science degree project conducted at the department of chemical engineering, at ntnu. There are multiple types of reformers in development but the most common in industry are autothermal reforming atr and steam methane reforming smr. Optimization of a methane autothermal reformingbased. A methane reformer is a device based on steam reforming, autothermal reforming or partial oxidation and is a type of chemical synthesis which can produce pure hydrogen gas from methane using a catalyst. This dissertation presents initial developments on ngr modelling in gproms.
Proven autothermal reforming technology for modern large. An autothermal reformer for converting a fuel into a reformate stream comprising hydrogen comprises a a closed vessel having a top end and a bottom end, the vessel comprising at least one insulation layer adjacent the interior surface of the vessel. The two main reformers, the steam methane reformer smr and the autothermal reformer atr were modelled. With regard to methane reformingbased hydrogen production processes, a combination of partial oxid ation and steam reforming of methane in an autothermal reform ing atr reactor has recently become more popular. Reactor system of a petroleum naphtha catalytic reforming plant. Autothermal reforming of methane on rhodium catalysts.
Autothermal reforming atr prototype for pure hydrogen production. However, further research is required to optimize the performance of autothermal reformers and accurate models of reactor performance must be developed and validated. This feature makes atr useful for many applications, and it has been proven industrially to provide quality syngas for largescale plants. The modeling, kinetic analysis, and simulation of atr o f methane for prescribed reactors have been studied 1012. The reactor design of the atr, as well as oxygenblown secondary reformers, consists of a burner, a.
Preliminary modeling and design of an autothermal reformer. Twosection reactor model for autothermal reforming of. Abstract the conceptual design of compact, standalone autothermal reforming systems using methanol is presented. Keywords autothermal reforming, synthesis gas, reactor modeling. Pdf the steadystate operation of the autothermal reformer is. The proposed mathematical has been checked successfully against data available in the open literature. The feed gas enters an annular region around the packed bed, but flows in the opposite direction from that in the packed bed.
Autothermal reforming of natural gas to synthesis gas reference. Operating data used to identify best design and to tune the design. Microkinetic analysis for model reduction marm dixita, renika baruaha, dhrupad parikha, sudhanshu sharmaa, atul bhargava,1 aenergy systems laboratory, iit gandhinagar, ahmedabad, gujarat, india abstract methane autothermal reforming has been studied using comprehensive, detailed microkinetic. In particular, great effort was devoted to the design of the delivery system for liquid hydrocarbons, in order to obtain a quick vaporization, an uniform reactants. To better understand diesel reforming and the chemistry involved, we have investigated the autothermal reforming of several major diesel constituents in a kilowattscale reactor. Steammethane reforming is practiced industrially using several different reactor designs. The gtl plant design has two parallel trains each consisting of a world scale air separation plant, an autothermal reformer, and a slurry phase fischertropsch reactor. Standalone autothermal reforming atr is advantageous because it does not require the supply or dissipation of thermal energy to or from the reaction. Autothermal reforming atr is a lowinvestment process using a simple reactor design. Describes the operation and the equations used to model an autothermal reactor. Autothermal reforming, or atr, combines steam methane reforming and partial oxidation into a single reactor. Change of the hotspot point due to the catalyst degradation was investigated and it could be used to design an adaptive controller. The thesis studies the simulation, optimization and control structure design using stepwise approach of skogestad.
Steam methane reforming smr and autothermal reformer atr are two industrial examples of the primary and secondary reformers, respectively. Catalytic partial oxidation cpox requires the use of a catalyst, and the. Autothermal reforming the use of autothermal reformers in syngas manufacture for ammonia and methanol production began in. Determination of optimal process flowrates and reactor design for autothermal hydrogen production in a heatintegrated ceramic microchannel network. Castaldi earth and environmental engineering hksm, columbia university, 500 west 120th street, new york, 10011 ny. The unisim process simulator was also used for the optimization of the process in only mode. Design and control of standalone autothermal reforming. Thermodynamic analysis of autothermal reforming of synthetic. Model versus experiment results were compared for three cases.
Production of hydrogen simultaneous separationreaction. A novel reactor type for autothermal reforming of diesel fuel. Vanden bussche in a fixed bed reactor lurgi technology. Thermodynamic assessment and autothermal reactor design. The influence of the main operating variables on the reactor performance is studied. Autothermal reforming has been widely used for the production of ammonia and methanol. Autothermal reforming atr is an important industrial process used to produce syngas with a low h2co ratio from 1. Autothermal reforming atr syngas generation catalystbased syngas generation through partial oxidation and subsequent reforming of gaseous feed autothermal reforming atr is a process for producing syngas, composed of hydrogen and carbon monoxide, by partially oxidizing a hydrocarbon feed with oxygen and steam and subsequent catalytic. Autothermal reforming atr, based on mixing air in with the steamfuel mixture, is an autothermal adaptation of steam reforming.
Autothermal reformer an overview sciencedirect topics. Proven autothermal reforming technology for modern largescale methanol plants per juul dahl. A new multicylinder microchamber reactor is designed on autothermal reforming of methane for hydrogen production, and its performance and thermal behavior, that is, based on the reaction mechanism, is numerically investigated by varying the cylinder radius, cylinder spacing, and cylinder layout. Pdf modeling an simulation of an autothermal reformer.
A novel reactor concept with autothermal operation is presented for the simultaneous production of ethylene by oxidative coupling ocm and synthesis gas by steam reforming of methane srm. Based on specific conditions of maximum waste heat recovery, the optimization algorithm for maximizing hydrogen yield is obtained. An original design of atr membrane reactor has been developed. The various reactor designs, fuel delivery systems and catalysts and. Modak department of chemical engineering indian institute of science, bangalore. In any manufacturing process where there is a chemical change.
Autothermal reactor learncheme educational resources. Prereforming prereforming is the term applied to the low temperature steam reforming of hydrocarbons in a simple adiabatic reactor using highly active, nickel based catalyst, which promotes the steam reforming reaction at low temperatures. Partial oxidation reactions occur in a region of the reactor referred to as the. Basic objectives in design of a reactor in chemical engineering physical operations such as fluid flow, heat transfer, mass transfer and separation processes play a very large part. Hence, the autothermal reactor is more compact and practical for use in the methanol production process11. Autothermal reforming of gasoline for fuel cell applications.
Autothermal reforming ofjp8 in a catalytic fins reactor federico barrai, marco j. There are multiple types of reformers in development but the most common in industry are autothermal reforming atr and steam methane. Using this model, the reactor design is performed and key operational parameters are investigated in order to increase both h 2 yield. The model was developed with experimental data from temperature profiles along the reactor and product composition co2, co, and h2 formation. Because co is denatured to h2 of equivalent mol volume in the poststage shift reactor of an autothermal reformer. Maarten biesheuvel and gert jan kramer shell global solutions international b. On the other hand, the process of combined reforming utilizes both of primary and secondary tools for production of synthesis gas, as it is commonly practiced in ammonia manufacturing. Haldor topsoe autothermal reformingbased process 17. Compact multifuel autothermal reforming catalytic reactor for h2. Effect of catalytic cylinders on autothermal reforming of. Autothermal reforming an overview sciencedirect topics. Proven atr technology for modern largescale methanol plants. Reforming of diesel fuel for transportation applications. Pre reforming pre reforming is the term applied to the low temperature steam reforming of hydrocarbons in a simple adiabatic reactor using highly active, nickel based catalyst, which promotes the steam reforming reaction at low temperatures.
Autothermal cyclic reforming and h2 refueling system. Toyo mrfz methanol reactor design 96 toyos methanol synthesis catalyst 98 reaction conditionsparameters 98. Determination of optimal process flowrates and reactor. Syncor autothermal reformer atr autothermal reforming at low steamtocarbon ratio the majority of the worlds syngasproducing plants apply steam methane reforming, with the specific type of reforming technology depending on application and operating conditions. Autothermal reforming atr syngas generation air liquide. A novel reactor type for autothermal reforming of diesel. These challenges result from the physical and chemical properties of diesel fuel. Diesel reforming poses several unique technical challenges, however. Autothermal reforming of natural gas to synthesis gas. The process was developed to produce a syngas intermediate from natural gas to synthesize methanol, ammonia, and fischertropsch liquids, due to its production of a syngas with a typical h 2 co ratio of about 2.
Developed in the late 50s, atrs main application was for ammonia and methanol syntheses. In this autothermal reactor, an exothermic reaction takes place in a packed bed of catalyst a plug flow tubular reactor. In particular, the technical approach used for the design and execution of the demonstration plants and the relevant peculiarities are outlined. Nonthermal plasmaassisted partial oxidation of methane. Optimization of a methane autothermal reformingbas ed hydrogen. Mann prepared by sandia national laboratories albuquerque, new mexico 87185 and livermore, california 94550 sandia is a multiprogram laboratory operated by sandia corporation. Sep 24, 20 steam reforming types of reformer design 1. However, for reactor design and catalyst development, nonequilibrium reactor modeling is required. Standalone autothermal reforming atr is advantageous because it does not require the supply or. A mathematical model for an autothermal reforming atr fuel processor has been developed to study the transient response of the reactor for gasoline reforming.
The process is sootfree due to burner design and fixedbed catalyst. Advanced modelling and optimisation of natural gas reforming. Autothermal reactor operation if a reaction requires a relatively high temperature before it will proceed at a. Autothermal reactor learncheme educational resources for. Modeling a novel combined solid oxide electrolysis cell. One of the main advantage of using an atr is the low steamcarbon ratio and hence a smaller and more compact reactor size lowering the capex. Production of hydrogen platefin reformer catalyst can be a surface coating or a porous insert. Reformer, temperature control, autothermal, methanol, copperzinc. Kinetics, catalysis and mechanism of methane steam reforming thesis submitted to the faculty of the. Methanol plant process layout with topsoe twostep reforming 14. Pdf the autothermal low temperature catalytic partial oxidation of methane was investigated in a bench scale reactor 1 kw th power over a. The lower operating temperature of catalytic autothermal reforming has several advantages including less complicated reactor design, wider choice of materials for. Using this model, the reactor design is performed and key operational parameters are investigated in order to increase both h 2 yield and h 2 co selectivity. The autothermal reforming technology has been widely discussed in the past on con.
The reactor model considers a mass balance equation for each component, and the. We also present and validate a smallscale reactor model for the autothermal reforming of methane atr. Hydrogen production via autothermal reforming atr is particularly attractive for applications that demand a quick startup and response time in a compact size. The paper describes the pilot plant concept, its main design features, experiences. Mar 06, 20 describes the operation and the equations used to model an autothermal reactor. Reforming with steam catalytic natural gas and light hydrocarbons. The structuring of the catalytic functions inside a single catalyst. It is considered as the preferred technology for gas to liquid plants. The autothermal reformer reactor and the secondary reformer are very similar. Reformer, temperature control, autothermal, methanol, copperzinc oxide catalyst 1. Integrated autothermal reactor concepts for oxidative coupling and reforming of methane. The combined output from these two trains feeds a single train isocracker. A new multicylinder microchamber reactor is designed on autothermal reforming of methane for hydrogen production, and its performance and thermal behavior, that is, based on the reaction mechanism, is numerically investigated by varying the cylinder.
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